Course
Organization for Chemistry 51
Prerequisite. The prerequisite for
Chemistry 51 is Chemistry 2.
Grading and
Examination Practices.
The Final Grade. The grade will be determined as
follows: Recitation Grade 25%; Laboratory Grade 25%; Lecture Examinations 25%;
Final Examination 25%
Final letter grades for the course will be assigned by a course grading committee. It is the recitation instructor's responsibility to keep a record of all of the student's grades. To receive your grade after the course ends, give a stamped post card or envelop to your recitation teacher.
Recitation
Grade.
This grade will be based on the student's average score on recitation quizzes
and may also include the instructor's evaluation of the student's class
participation. All recitations must be attended. Absence from recitation is
subject to penalties.
Laboratory
Grade.
The laboratory instructor is responsible for determining the laboratory grade
and will include his assessment of your advance preparation, comprehension of
the experiment, aptitude for laboratory work, and your compliance with safety
regulations among several other criteria which will be explained to you by the
laboratory instructor. Penalties will be assigned for failure to attend lab
faithfully and do all of the assigned experiments.
Lecture
Examinations. There will be two uniform lecture examinations given to students in
all sections. Questions based on the reading assignments, the lectures, and the
laboratory experiments will be included. The examinations will be held during
the regular lecture hour. The dates of these examinations are shown in the
lecture schedule; the location of the examination rooms will be announced by
the lecturer.
Final
Examination. This examination will cover the assignments of the ENTIRE semester
including the laboratory work. There are no exemptions from the final
examination.
Illness
During Examinations. If you become ill during any examination and feel that you are unable
to complete it, notify a proctor immediately, write the words "I am
sick", and hand in you paper. Your paper will not be graded and you will
be considered absent from the examination. If you remain until the end of the
exam, your paper will be graded and your grade will not be changed by a later
claim of illness.
Absence
from Examinations. No make-up examinations are given to students who are absent from the
lecture examinations. Students who miss one of the exams with a valid excuse,
will be assigned a score for the exam missed on the basis of their performance
on the other lecture exam and on the final. A grade of zero for lecture will be given if both lecture exams are
missed.
In the event of absence from the final exam, you will need to apply to the academic Advisement Center for permission to take the make-up final examination given the following semester. If the recitation instructor has recorded an absent 50 grade or lower, permission will be denied.
Cheating. Any student found cheating on any quizzes
or exams will be given a failing grade. 7/05/01
Brooklyn College
Department of Chemistry
Chemistry 51 Lecture Schedule Fall 2001
Lecture Date Topic Reading Assignment
1 M 8-27-01 Structure
and Properties Ch.1
2 W 8-29-01 Classification
& Hydrocarbon 2.1-2.4; 3.1, 3.2, 3.6-3.11
Nomenclature. 5.3-5.5; 8.1, 8.3, 8.5, 8.7,
8.8.
Supplement
for Organic Chemistry Pages 2-8
Rotational Isomers
(conformations) 2.2, 12.3, 13.2;
3.3, 3.4, 3.5
3 W 9-05-01 Halogenation
of Methane 2.5-2.20.
Hybridization; Transition State 2.22-
2.24; omit 2.25
Qualitative & Quantitative
Analysis 2.26-2.30
4 M 9-10-01 Alkane
Halogenation. Reactions, 3.19-3.29,
3.13-3.18
Structure Determination; Analysis 3.32-3.34;
5 W 9-12-01 Stereochemistry 4.1 -4.16
Diastereoisomers, meso compounds 4.17-4.25
M & W 9-17 & 9-19-01 No Classes
W 09-26-01 No Classes
7 M 10-01-01 Alkyl Halides, Substitution Reactions 5.1-5.15
8 M 10-03-01 Carbocations & Reaction Mechanisms 5.16-5.24
M 10-08-01 No
Classes Columbus Holiday
9 T 10-09-01 Solvent Effects On Sn1 & Sn2 Reactions Ch.7
10 W 10-10-01 Nomenclature
of Alcohols, Ethers, 6.2, 6.3, 6.4,
6.16, 18.1-18.2
Carbonyl Compounds and Acids 19.1 -19.2. Supple. pgs.9-12
11 M 10-15-01 First Lecture Examination Chapters 1-5, 7.
12 W 10-17-01 Alcohols:
Synthesis & Reactions 6.1-6.15;
29.8
13 M 10-22-01 Ethers; Cyclic Ethers; Crown Ethers 6.16-6.23; 13.18-13.19
15 M 10-29-01 Electrophilic Additions to Alkenes 9.1-9.13; 10.2-10.3
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Chemistry 51 Lecture
Outline Fall
2001
Lecture Date Topic Reading Assignment
16 W 10-31-01 Radical Additions to Alkenes 9.14-9.27
17 M 11-05-01 Aldehydes and Ketones 18.1
-18.10
18 W 11-07-01 Aldehydes and Ketones 18.11
-18.22
19 M 11-12-01 Conjugation & Resonance 11.1-11.16
20 W 11-14-01 Dienes; Diels-Alder Reaction 11.17-11.26;
27.8
21 M 11-19-01 Second Lecture Examination Chapters
6, 8-11; 18
22 W 11-21-01 Alkynes Chapter
12
23 M 11-26-01 Cycloalkanes 13.1
-13.12
24 W 11-28-01 Cyclohexane Stereoisomerism 13.13-13.15;
13.25
25 M 12-03-01 Carbenes and Epoxides 13.16-13.
26 W 12-05-01 Structures via Spectroscopy 17.1-17.8
27 M 12-10-01 Proton Magnetic Resonance 17.9-17.14
omit 17.15-17.23
28 W 12-12-01 Organic Structure Determination 18.23
Final Exam 12-18-01 1:00-3:00 pm
(1)
R.T.
Morrison and R.N. Boyd, "Organic Chemistry", 6th Edition, Prentice
Hall, Englewood Cliffs, N.J. 07632,1992.
(2)
L.B.Gortler
and R.C.Tripp, Techniques & Experiments in Organic Chemistry, 2nd Edition, Avery Publishing Group Inc., Wayne,
N.J.
(3)
A
Study Guide to accompany Morrison & Boyd Organic Chemistry 6th Edition, Prentice
Hall, 1992
(4) Molecular Model Set for Organic Chemistry
Prentice Hall
The 1987 Supplement for Organic Chemistry 51 & 52 as prepared by the Brooklyn College Chemistry Faculty
is available only in the College Bookstore and is required for this course. 7-05-01
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Chemistry 51 Problem Assignments for Recitation Fall 2001
Week
1 Ch
1: 1.1 b, d, f, h; 1.2-1.13; pp 37-38 1-3; 5; 8; 9; 10; 11; 12; 13.
2 Ch.3:
3.1; 3.2; 3.5 a, b; 3.6 a; 3.7 a; pp 122-123, 1 a, d, i, j; 2 b, d, k;
Ch 5: 5.1; Ch.6: 1 a, b, c, d, e; 2c, d, e, f; 3
b, c; Ch.8: 8.1 a, b; 8.2 b, c, d;
pg. 245 pg. 282-283
Ch8: 8.3
a, b; Pg.315, 1 a, b, c; 2a,b, d.Ch.12: pg. 441 1 a, b
.
See nomenclature supplement pp 18-19: 1 a, c, d, e,
9; 2 a-c, f, 9, h; 3 a-f.
--------------------------------------------------------------------------------------------------------------
3 Ch.2:
2.1, 2.2, 2.6, 2.7, 2.9, 2.10; pages.75-76, 7, 8, 11e, 14, 15, 16, 17.
Ch.3: 3,3, 3.4 a, b; 3.8 a,
b; 3.9, 3.10; 3.12; 3.13 3.14 b, f; 3.16; 3.17; 3.18; 3.19
Pages 122-124, 5 a; 6; 7; 8
a, e, f; 9; 10 b; 14; 15; 20.
-------------------------------------------------------------------------------------------------------------
4 Ch.4:
4.1-4.10; 4.11 a, c, e; 4.12; 4.13; 4.14; 4.15. pgs 162-4, 1, 2, 3, 4 a, 6.
5 Ch.4:
4.16, 4.17, 4.18, 4.19, 4.20, 4.21, 4.22a, 4.23, 4.24; 8 a, c ,g, h, i; 9;
13 a, c, f, g; 14; 15.
6 Ch
5: 5.2, 5.3*, 5.4*, 5.5, 5.6, 5.7, 5.8, 5.9; pgs.211-2, 1,2,3, 4, 5, 6, 7, 8,
9, 10.
Ch.7: 7.1, 7.2, 7.3, 7.4*,
pages 271-272, 3, 4, 5, 6, 11.
7 Ch.6:
6.1- 6.2, 6.3, 6.4, 6.5, 6.6, 6.7, 6.8, 6.9, 6.10, 6.11,6.12, 6.13,6.14*.
pages 245-247, 4, 6, 7, 8 b, c, 9, 12, 13, 14, 17,
18.
8 Ch.8;
8.4, 8.5*, 8.6, 8.7, 8.8, 8.9, 8.10, 8.11, 8.12, 8.13, 8.14, 8.15, 8.16, 8.17,
8.18,8.19,8.20,pgs315-6, 1d,e, f, g, 2 3, 4, 5, 6, 7, 8, 9,10,11,12,13; 10.4 p 380
9 Ch.9:
9.1-9.9; 9.10 a, b, d; 9.11, 9.12, 9.13, 9.14, 9.15, 9.16, 9.17, 9.18;
pages 363-366, 1, 2, 3, 6, 8,16,17aj, 18a,e; 20d,e,f; 21 b,f,g.
Page 372. 10.1. Page 375. 10.2, 10.3. pages. 384-6, 1, 2, 3, 8, 12.
14, 15, 22, 24.
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Chemistry 51 Recitation
Assiqnments Fall
2001
Week
11 Ch.11:
11.1, 11.2,11.3, 11.4, 11.5, 11.6,11.7,11.8,11.9, 11.10*, 11.12*, 11.13,
11.15, 11.16, 11.17, 11.18,
11.19, 11.20, 11.21; p.422-4; 1, 2, 3 a, c, e, f, g, h;
5b,c,e;6b,c,e;7d;9a,c,d,e;10,11,
13, 14, 15, 17.
12 Ch.12:
12.1,12.2,12.3,12.4,12.5,12.6,12.7; p. 441-2; 1, 2, 3, 4, 5, 6, 7, 8, 9.
13 Ch.13:
13.1, 13.2,13.3, 13.4, 13.5, 13.6, 13.8,13.9,13.10, 13.11, 13.12,-.14.
Pg.488-489;1,
2,3a-h,3cj,ia-e,5,6,9,11,12a,b,e;13, 15,20,22;
14 Ch.13:
13.16, 13.17, 13.18, 13.19,13.20,13.21, 13.22, 13.23, 13.24a, b, c;
13.25, 13.26, 13.27, 13.28,
13.30, 13.31; p. 491 16, 17, 18, 19.
Ch.17: 17.2,17.3, 17.4, 17.7,
17.8, 17.9, 17.10, 17.12, 17.13, (17.11), 17.15,
17.16, Pg.643-655, 1 a, b,
c, d, e, f; 21 (p.648), 23 (p.650) 27 (p.653 & 654)
Ch.18: p.706, 30, 32, 33,
Notices of interest and sample examinations from previous semesters using this textbook's sixth edition will be posted from time to time
on the bulletin board adjacent to the third floor
stock room window (3307 N) .
and the last day to drop a course with a W grade is
Tuesday, November 13, 2001
7/05/01
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Laboratory Assignments
Read Chapter 1
of the Laboratory Manual before coming to the laboratory for the first time. You must be familiar with
the safety precautions (section 1.2), the rules for working in the laboratory
(section 1.3), and you are expected to have a pair of safety glasses, a
padlock, and a hard bound laboratory note-book with numbered pages. Ten other items which should be brought
from home such as matches, towel, soap, band aids etc. are listed in section 1.8 on pages 9-10.
Students are expected to have part of the notebook write-up done in
advance.Otherwise the instructor may ask the student to leave the laboratory.
Lab Reading Assignments
Period Experiment in the Laboratory Manual
1 Check-in: Simple Distillation;
unknown optional Ch.1
& Ch. 2 (1.20 M & B)
2 Comparison of Simple & Fractional Distillation Ch.3; 3.4-1; 3.42 optional
Thermometer calibration via melting points 7.4-1 (read pgs 35-6 &
41)
Determination of
melting points of mixtures 7.42 & 1.18 M & B
3 Recrystallization of Acetanilide and Benzoin 7.4-3, 7.4-4; 1.21 M & B
4 Purification of an Unknown by Recrystallization 7.4-5
Identification by m.p. determination
5 Extraction of adipic acid from water by ether 8.1, 8.2, 8.3-1, 8.3-2,8.3-4
6 Separation of a mixture of an unknown acid 8.41, 8.4-2, 8.4-3
and an unknown neutral hydrocarbon
7 Separation of Fluorene-Fluorenone
mixture 9.1; 9.2, 9.3-1;
8 The Preparation of 1-Bromobutane 12.1-12.2-1; pages
69-72
Read Chapter 6 on the drying of liquids pages 31-32; 6.1; 6.2
9 The Preparation of Cyclohexene Ch. 13. Pages 73-76
Read Chapter 6 on
the drying of liquids again
10 The Oxidation of an Unknown Alcohol Ch. 14, pages 77-81
11 Preparation of Unknown Ketone Derivatives 14.2-2, pg 80
12 The Synthesis of Triphenylmethanol Ch.17, pgs 89-91
Removal of impurities by steam distillation Ch. 5 pgs 27-30
13 Purification of Triphenylmethanol
Identification of an Unknown By
Infrared Spectroscopy
14 Check Out. No Experimental Work Is Permitted 7/05/01
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