132.
A. Sánchez, M. Fang, A. Ahmed, and R. A. Sánchez-Delgado*, “Hydrogenation of arenes,
N-heteroaromatic compounds, and alkenes catalyzed by rhodium
nanoparticles supported on magnesium oxide”, 2013
(submitted).
131.
M. Fang and R. A. Sánchez-Delgado,* "Ruthenium nanoparticles
supported on magnesium oxide: a versatile and recyclable
catalyst for hydrogenation of mono-/poly-cyclic arenes,
N-heteroaromatics and S-heteroaromatics" 2013 (submitted).
130.
C. S. K. Rajapakse, M. Lisai, C. Deregnaucourt, V. Sinou, C.
Latour, J. Schrével, and Roberto A. Sánchez-Delgado* “New
N-aryl-4-aminoquinolines display high in vitro activity
against chloroquine-sensitive and chloroquine-resistant
Plasmodium falciparum and low toxicity to normal mammalian
cells” 2013 (submitted)
129.
E. Robles-Escajeda, A. Martínez, A. Varela-Ramirez, R. A.
Sánchez-Delgado, and R. J. Aguilera,* “Analysis of the
cytotoxic effects of ruthenium-ketoconazole and
ruthenium-clotrimazole complexes on cancer cells” Cell Biol. Toxicol. 2013, 29, 431-443.
128.
J. G. Estrada and R. A. Sánchez-Delgado,* “Spectroscopic Study of
the Interactions of Ruthenium-Ketoconazole Complexes of Known
Antiparasitic Activity with Human Serum Albumin and
Apotransferrin”,
J. Mex. Chem.
Soc.,
2013, 57,
169-174.
127.
R. A. Sánchez-Delgado* y V. Medialdea, “La química inorgánica a
la búsqueda del “Magic Bullet” en contra de enfermedades
desatendidas; el caso de Latinoamérica” en A. Ponte Sucre y L.
G. Rodríguez (Eds.) “Las Tecnologías de Información y
Comunicación en el combate de las enfermedades desatendidas en
América Latina y el Caribe: Aportes desde la investigación en
ciencias de la salud”. Fundación
Telefónica-Ariel, Barcelona, España 2013, in press.
126.
E. Iniguez, A. Sánchez, M. A. Vasquez, A. Martínez, J. Olivas,
A. Sattler, R. A. Sánchez-Delgado*, and R. A. Maldonado*, “The Metal-Drug Synergy:
New RutheniumII Complexes of Ketoconazole are Highly Active
against Leishmania major and Trypanosoma cruzi and Non-toxic
to Human or Murine Normal Cells” J. Biol. Inorg. Chem. 2013, 18, 779-790.
125.
R. Rahi, M. Fang, A. Ahmed and R. A. Sánchez-Delgado*, “Hydrogenation of
quinolines, alkenes, and biodiesel by palladium nanoparticles
supported on magnesium oxide.” Dalton Trans. 2012, 41, 14490-14497.
124. A.
Martínez, T. Carreon, E. Iniguez, A. Anzellotti, A. Sánchez,
M. Tyan, A. Sattler, L. Herrera, R. A. Maldonado* and R. A.
Sánchez-Delgado*, “Searching for new chemotherapies for
tropical diseases: Ruthenium-clotrimazole complexes display high
in vitro activity against Leishmania
major and Trypanosoma
cruzi and low toxicity toward normal mammalian cells.” J, Med. Chem. 2012, 55, 3867-3877.
123. L.
Glans, A. Ehnbom, C. de Kock, A. Martínez, J. Estrada, P. J.
Smith, M. Haukka, R. A. Sánchez-Delgado* and E. Nordlander*,“Ruthenium(II)
arene complexes with chelating chloroquine analogue ligands:
Synthesis, characterization and in vitro antimalarial activity.” Dalton Trans. 2012, 41, 2764-2773. PMC3303165.
122. B. Demoro,
C. Sarniguet, R. Sánchez-Delgado, M. Rossi, D.
Liebowitz, F. Caruso,
C. Olea-Azar, V. Moreno, A. Medeiros, M.
A. Comini, L. Otero,* D. Gambino,* “New organoruthenium complexes
with bioactive thiosemicarbazones as co-ligands: potential
anti-trypanosomal agents.” Dalton Trans. 2012, 41, 1534-1543. PMC3299570
121. M.
Navarro,* W. Castro, A. R, Higuera-Padilla, A. Sierraalta, M.
J. Abad, P. Taylor and R. A. Sánchez-Delgado, “Synthesis,
characterization and biological activity of trans-platinum (II)
complexes with chloroquine”, J. Inorg. Biochem. 2011, 105, 1684-1691. PMC3294264.
120. M.
Fang, N. Machalaba and R A. Sánchez-Delgado,*
“Hydrogenation of arenes and N-heteroaromatic compounds over
ruthenium nanoparticles on poly(4-vinylpyridine): a versatile
catalyst operating by a substrate-dependent dual site mechanism”
Dalton Trans. 2011, 40, 10621–10632.
119. M.
Navarro,* W. Castro, A. Martínez and R. A. Sánchez-Delgado,
“The Mechanism of Antimalarial Action of [Au(PPh3)(CQ)]PF6”:
structural effects and increased drug lipophilicity enhance heme
aggregation inhibition at lipid/water interfaces.” J. Inorg. Biochem. 2011, 105, 276-282. PMC 3038622.
118. A.
Martínez, J. Suárez, T. Shand, R. S. Magliozzo and R. A.
Sánchez-Delgado*, “Interactions of
Arene-Ru(II)-Chloroquine Complexes of Known Antimalarial and
Antitumor Activity with Human Serum Albumin (HSA) and
Transferrin”, J. Inorg.
Biochem. 2011,
105, 39-45. PMC 2990986
117. A.
Martínez, C. S. K. Rajapakse, A. Varela-Ramirez, C. Lema, R.
Aguilera and R. A. Sánchez-Delgado*, “Arene-Ru(II)-Chloroquine
Complexes Interact With DNA, Induce Apoptosis Against Human
Lymphoid Cell Lines
and Are Less Toxic to Normal Mammalian Cells than Chloroquine”,
J. Inorg. Biochem. 2010, 104, 967-977. PMC 2910123.
116. A.
Martínez, C. S. K. Rajapakse, D. Jalloh, C. Dautriche and R.
A. Sánchez-Delgado*, The antimalarial activity of
Ru–chloroquine complexes against resistant Plasmodium falciparum
is related to lipophilicity, basicity, and heme aggregation
inhibition ability near water/n-octanol interfaces, J. Biol. Inorg. Chem.
2009, 14, 863-871.
115. S.
Jiménez, J. A. López, M. A. Ciriano, C. Tejel,* A. Martínez,
and R. A. Sánchez-Delgado, “Selective Hydrogenation of
Cinnamaldehyde and Other a,b-Unsaturated Substrates Catalyzed by
Rhodium and Ruthenium Complexes” Organometallics, 2009, 28, 3193-3202.
114. C. S. K. Rajapakse, A.
Martínez, B. Naoulou, A. A. Jarzecki, L. Suárez, C.
Deregnaucourt, V. Sinou, J. Schrével, E.
Musi, G. Ambrosini, G. K. Schwartz and R. A. Sánchez-Delgado*,“Synthesis, Characterization and
in vitro Antimalarial and Antitumor
Activity of New Ruthenium(II) Complexes of Chloroquine”,Inorg. Chem. 2009, 48, 1122-1131. PMC 2673146
113. V.
R. Landaeta,* F. López-Linares, R. Sánchez-Delgado, C.
Bianchini, F. Zanobini and M. Peruzzini,*
“Synthesis and
Characterization of New Rhodium and Iridium Complexes with
Trianisylphosphine, PAn3, and
Evaluation of their Catalytic Behavior in the Homogeneous
Hydrogenation of Cinnamaldehyde”, J. Mol. Catal. (A) 2009, 301, 1-10; Featured
as Editor’s Choice Paper.
112. A.
Martínez, Ch. S. K. Rajapakse, B. Naoulou, Y. Kopkalli, L.
Davenport and R. A. Sánchez-Delgado.* “The Mechanism of
antimalarial action of the Ru(II)-chloroquine complex [RuCl2(CQ)]2”,
J. Biol. Inorg. Chem. 2008, 13, 703-712. PMC 2409194.
111. R. A.
Sánchez-Delgado,* N. Machalaba and N. Ng-a-qui. “Hydrogenation of Quinoline by
Ruthenium Nanoparticles immobilized on poly(4-vinylpyridine)”.
Catal Commun. 2007, 8, 2115-2118. PMC 2390998.
110. M.
Rosales,* A. González, Y.
Guerrero, I. Pacheco and R. A. Sánchez-Delgado. “Kinetics
and mechanisms of homogeneous catalytic reactions. Part 6.
Hydroformylation of 1-hexene by use of Rh(acac)(CO)2/dppe [dppe
= 1,2-bis(diphenylphosphino)ethane] as the precatalyst”. J. Mol. Catal. A: Chem.
2007, 270, 241-249.
109. M.
Rosales,* J. A. Durán, A.
González, I. Pacheco and R. A. Sánchez-Delgado. “Kinetics
and mechanisms of homogeneous catalytic reactions. Part 7.
Hydroformylation of 1-hexene catalyzed by cationic complexes of
rhodium and iridium containing PPh3”. J. Mol. Catal. A: Chem.
2007, 270, 250-256.
108. R.
A. Sánchez-Delgado. “Homogeneous Hydrogenation by Defined
Metal Clusters”. Invited Chapter in “Handbook of Homogenoeus
Hydrogenation”, K. Elsevier and J. G. de Vries, Eds. Wiley-VCH:
Weinheim (2007). Vol.
1, Ch. 8, pp. 199-215.
107. R.
A. Sánchez-Delgado. “Hydrodesulfurization and
Hydrodenitrogenation”. Invited Chapter in Comprehensive
Organometallic Chemistry III, R. H. Crabtree and D. M. P.
Mingos, Eds. Elsevier: Oxford (2006). ISBN: 008044590X. Vol. 1, Ch.
1.27, pp. 759-800.
106. F.
López-Linares, J.
Urdaneta, V. Sánchez, and R. A. Sánchez-Delgado.
“Hydrogenation of a,b-unsaturated carbonyl substrates by use of
[Ir(COD)(PPh3)2]PF6 in 1-butyl-3-methylimidazolium
hexafluorophosphate”. Ciencia
2006, 14, 26-30.
105. V.
Landaeta, B. K. Muñoz, M. Peruzzini, V. Herrera, C. Bianchini,
and R. A. Sánchez-Delgado. “Imine hydrogenation by
tribenzylphosphine rhodium and iridium complexes”. Organometallics 2006, 25, 403-409.
104. V,
Landaeta, M. Peruzzini, V. Herrera, C. Bianchini, R. A.
Sánchez-Delgado, A. E. Goeta,
and F. Zanobini. “Synthesis, characterization and
reactivity of tribenzylphosphine rhodium and iridium complexes”.
J. Organomet. Chem. 2006, 691, 1039-1050.
103. P. J.
Baricelli, K. Segovia, E.
Lujano, M. Modroño-Alonso, F. López-Linares, and R. A.
Sánchez-Delgado. “Synthesis and characterization of
[HRu(CO)(CH3CN)(TPPTS)3]BF4.
Catalytic properties in the aqueous-biphasic hydroformylation of
olefins”. J. Mol. Catal. A: Chem. 2006, 252, 70-75.
102. M.
Vietes, P. Buccino, L. Otero, M. González, O. E. Piro, R.
Sánchez-Delgado, C. M. R. Sant’Anna, E. J. Barreiro, H.
Cerecetto, and D. Gambino. “Chemoselective hydrolysis of
the imine moiety in salicylaldehyde semicarbazone promoted by
ruthenium. Inorg. Chim.
Acta 2005, 358, 3065-3074.
101. P.
J. Baricelli, F. López-Linares, A. Bruss, R. Santos, E. Lujano and R. A.
Sánchez-Delgado. Biphasic hydroformylation of olefins by
the new binuclear water-soluble rhodium complex
[Rh(m-Pz)(CO)(TPPTS)]2. J. Mol. Catal. A: Chem. 2005, 239, 130-137.
100. M.
Rosales, A. González, B.
González, C. Moratinos, H. Pérez, J. Urdaneta and R. A.
Sánchez-Delgado. Hydroformylation of alkenes with
paraformaldehyde catalyzed by rhodium-phosphine complexes. J. Organometal. Chem.,
2005, 690, 3095-3098.
99. P.
J. Baricelli, E. Lujano, M. Modroño, A. C. Marrero, Y. M.
García, A. Fuentes and R. A. Sánchez-Delgado,
Rhodium-catalyzed hydroformylation of C6 alkenes and alkene
mixtures. A comparative study in homogeneous and aqueous
biphasic media using PPh3, TPPTS and TPPMS ligands. J. Organometal. Chem.,
2004, 689, 3782-3792.
98. M.
Rosales, T. González, R. Atencio and R. A. Sánchez-Delgado,
Synthesis and reactivity of iridium complexes with pyridine and
piperidine ligands: Models for hydrodenitrogenation Dalton Transactions, 2004, 2952-2956.
97. M.
Navarro, F. Vásquez, R. A. Sánchez-Delgado, H. Pérez, V.
Sinou, J. Schrevel, Toward a Novel Metal-Based
Chemotherapy against Tropical Diseases. 8. Synthesis and in vitro antimalarial
activity of new gold-chloroquine complexes. J. Med. Chem., 2004, 47, 5204-5209.
96.
M. Strasberg-Rieber, A. Anzellotti, R. A.
Sánchez-Delgado and M. Rieber, “Apoptosis induced by
Ruthenium(II) ketoconazole irrespective of p53 status is
enhanced in non-susceptible carcinoma by monoclonal antibody to
EGF receptor.” Int. J.
Cancer, 2004, 112, 376-384.
95.
E. Cabrera, H. Cerecetto, M. González, D. Gambino, P.
Noelia, L. Otero, B. Parajón-Costa, A. Anzellotti, R. A.
Sánchez-Delgado, A. Azqueta, A. López de Cérain and A. Monge,
“Ruthenium(II) nitrofurylsemicarbazone complexes: new DNA
binding agents.” Eur. J.
Med. Chem., 2004,
39, 377-382.
94.
P. Baricelli, M. Rodríguez, E. Lujano, A. Fuentes and
R. A. Sánchez-Delgado, “Synthesis and characterization of
Ru(H)2(CO)2(TPPMS)2 and
applications to the hydroformylation of alkenes” Appl. Catal. (A): General
2004, 263, 187-191.
93. R.
A. Sánchez-Delgado and A. Anzellotti, “Metal Complexes as
chemotherapeutic agents against tropical diseases:
trypanosomiasis, malaria and leishmaniasis”. Minirev. Med. Chem., 2004, 4, 23-30.
92.
R. A. Sánchez-Delgado, A. Anzellotti and L. Suárez,
“Metal complexes as chemotherapeutic agents against tropical
diseases: malaria, leishmaniasis and trypanosomiasis”. Invited
Chapter in Metal Ions in
Biological Systems, Eds. H. Siegel and A. Siegel, Marcel
Dekker: New York, 2004,
Vol. 41(“Metal Ions and
their Complexes in Medication”) 379-419.
91.
L. Otero, P. Noblia, D. Gambino, H. Cerecetto, M.
González, R. Sánchez-Delgado, E. E. Castellano and O. E. Piro,
“New Rheniun(V) Nitrofuryl Semicarbazone Complexes. Crystal
Structure of [ReOCl2(PPh3)(3-(5-Nitrofuryl)acrolein
semicarbazone)]. Z.
Anorg. Allg. Chem. 2003,
629, 1033-1038.
90.
R. A. Sánchez-Delgado, “Hydrodesulfurization by
Homogeneous Catalysts” Invited Chapter in “Encyclopedia of
Catalysis”, I. T. Horvath, Ed., John Wiley & Sons, New York,
2003.
89.
M. Alías, P. J. Daff, M. Paneque, M. L. Poveda,* E.
Carmona,* P. J. Pérez, V. Salazar, E. Gutierrez-Puebla, M.
Angeles Monge, C. Ruiz-Valero, Y. Alvarado, R. Atencio and R.
A. Sánchez-Delgado, “C-C Bond forming reactions of
Ir(III)-alkenyls and nitriles or aldehydes. Generation of
reactive hydride- and alkyl-alkylidene compounds and observation
of a reversible 1,2-H shift in stable hydride-alkylidene Ir(III)
complexes.” Chem. Eur. J. 2002, 8, 5132-5146.
88.
M. Esther Morilla, G. Morfes, M. C. Nicasio, T. R.
Belderrain, M. Mar Díaz-Requejo, A. Tiripicchio, R.
Sánchez-Delgado* and P. J. Pérez*, “Intramolecular
dealkylation of chelating diamines with Ru(II) complexes.” Chem. Commun. 2002, 1848-1849.
87.
Navarro, M., Cisneros-Fajardo, E., Lehmann, T.,
Sánchez-Delgado, R. A., Atencio, R., Silva, P., Lira, R.,
Urbina, J. A., Toward a Novel Metal-Based Chemotherapy
against Tropical Diseases. 6. Synthesis and Characterization of
New Cu(II) and Au(I) Clotrimazole and Ketoconazole Complexes and
Evaluation of their Activity against Trypanosoma cruzi. Inorg. Chem. 2001, 40, 6879-6884
86.
M. Navarro, T. Lehmann, E. J. Cisneros, A. Fuentes, R.
A. Sánchez-Delgado*, P. Silva and J. A. Urbina. “Toward a
Novel Metal Based Chemotherapy Against Tropical Diseases. 4.
Synthesis and Characterization of New Ru(II) and Ru(III) Clotrimazole and
Ketoconazole Complexes and Evaluation of their Activity Against
Trypanosoma cruzi.” Polyhedron 2000, 19, 2319-2325
85. R.
A. Sánchez-Delgado and M. Rosales, “Kinetic Studies as a
Tool for the Elucidation of the Mechanisms of Metal
Complex-Catalyzed Homogeneous Hydrogenation Reactions”. Coordination Chemistry
Reviews 2000, 196, 249-280.
84.
R. A. Sánchez-Delgado, “Complejos Metálicos en
Catálisis y en Química Medicinal” Revista de la Sociedad
Venezolana de Química 1999, 22, 7-13.
83.
R. A. Sánchez-Delgado, “Algunos Comentarios Acerca
de la Publicación y la Evaluación de la Investigación en
Ciencias Experimentales. ¿Son Estos Aplicables a las
Matemáticas?” Boletin de
la Asociación Matemática Venezolana 1999, VI, 47-53.
82. C.
Bianchini, A. Meli, S. Moneti, W. Oberhauser, F. Vizza, V.
Herrera, A. Fuentes, and R. A. Sánchez-Delgado, “Mimicking
the HDS Activity of Ruthenium-Based Catalysts 2: The
Hydrogenation of Benzo[b]thiophene
to 2,3-Dihydrobenzo[b]thiophene.” J. Am. Chem. Soc. 1999, 121, 7071-7080.
81.
E. Paez, A. Andriollo, F. Lopez-Linares, R. E.
Galiasso, J. A. Revete, R. A. Sanchez-Delgado, and A. Fuentes, “The reduction of
nitrogen- and sulfur-containing heteroaromatic compounds in a
biphasic medium using a Group VIII hydrosoluble organometallic
complex.” Am. Chem. Soc.
Div. Fuel. Chem. Symp. Prepr. 1998, 43, 563-567.
80.
R. A. Sánchez-Delgado,* M. Navarro, K. Lazardi, R.
Atencio, M. Capparelli, F. Vargas, J. A. Urbina,* A. Bouillez,
A. F. Noels and D. Masi, “Toward a Novel Metal Based
Chemotherapy Against Tropical Diseases. 4. Synthesis and
Characterization of New Metal Clotrimazole Complexes and
Evaluation of their Activity Against Trypanosoma cruzi.” Inorg. Chimica Acta 1998, 275-276, 528-540.
79.
M. Navarro y R. A. Sánchez Delgado, “Complejos de
Coordinación como Posibles Agentes Quimioterapéuticos en
Medicina Tropical” Rev.
Soc. Ven. Quim. 1997,
20, 10-14.
78.
V. Herrera, A. Fuentes, M. Rosales, R. A.
Sánchez-Delgado*, C. Bianchini, A. Meli and F. Vizza,
"Homogeneous Hydrogenation of Benzothiophene by Use of Rhodium
and Iridium Complexes as the Catalyst Precursors: Kinetic and
Mechanistic Aspects, Organometallics
1997, 16, 2465-2471.
77. M.
Navarro, H. Pérez and R. A. Sánchez-Delgado*, "Toward a
Novel Metal-Based Chemotherapy against Tropical Diseases. 3.
Synthesis and Antimalarial Activity in vitro and in vivo of the New
Gold-Chloroquine Complex [Au(PPh3)(CQ)]PF6."
J. Med. Chem. 1997, 40, 1937-1939
76.
R. A. Sánchez-Delgado*, M. Medina, F. López-Linares and
A. Fuentes, “The Chemistry and Catalytic Properties of
Ruthenium and Osmium Complexes. Part 7. Regioselective
Hydrogenation of Cinnamaldehyde (3-phenyl-2-propenal) Catalyzed
by Ru and Os Triphenylphosphine Complexes in Homogeneous
Solution and by Meta-sulfonatophenyl-diphenylphosphine
(TPPMS)
and Tris-meta-sulfonato-phenylphosphine
(TPPTS)
Derivatives in an Aqueous Biphasic System.” J. Mol. Catal. 1997, 116, 167-177.
75. Bianchini,
J. A. Casares, A Meli, V. Sernau, F. Vizza and R. A.
Sánchez-Delgado, “Efficient Rhodium Catalysts for the
Hydrogenolysis of Thiophenic Molecules in Homogeneous Phase.” Polyhedron, 1997, 16, 3099-3114.
74. Bianchini,
A. Meli and R. A. Sánchez-Delgado, “Catalytic
Hydrogenolysis of Thiophenic Molecules to Thiols by Soluble
Metal Complexes”, en Transition
Metal Sulfur Chemistry: Biological and Industrial Significance
(E. Stiefel and K. Matsumoto, Eds.), 1996, ACS Symp. Ser.
Vol. 653, Ch. 10, American Chemical Society, Washington D. C.
73.
R. A. Sánchez-Delgado*, M. Navarro, H. Pérez* and J. A.
Urbina, "Toward a Novel Metal-Based Chemotherapy against
Tropical Diseases. 2. Synthesis and Antimalarial Activity in vitro and in vivo of New
Ruthenium- and Rhodium-Chloroquine Complexes." J. Med. Chem. 1996, 39, 1095-1099.
72.
Y. Alvarado, P. J. Daff, P. J. Pérez, M. L. Poveda, R.
Sánchez-Delgado, and E. Carmona, "Iridapyrrole Complexes
via 1,3-Dipolar Addition of Iridium-Alkenyls to Acetonitrile" Organometallics, 1996, 15, 2192-2194.
71.
R. A. Sánchez-Delgado*, R. Gomes da Rosa, and E.
Ocando-Mavarez, "The Mechanism of the Mild
Rhodium-catalyzed Carbonylation of N-alkylallylamines to
-Butyrolactams under CO/H2."
J. Mol. Catal. 1996, 108, 125-129.
70. Argüello,
A. Bolaños, F. Cuenu, M.
Navarro, V. Herrera, A. Fuentes, and R. A. Sánchez-Delgado*,
"Synthesis, Characterisation and some Catalytic Properties of
Ru(II) Complexes Ru(PPh3)2Cl2(L)2 (L
= 4-tBu-py, 4-vinyl-py, 4-CN-py, 4-Me-py, 3-Me-py, L2 = 4,4' bipy]. Kinetics
of Cyclohexene Hydrogenation Catalysed by Ru(PPh3)2Cl2(4-tBu-py)2."
Polyhedron, 1996, 15, 909-915.
69.
Bianchini*, J. A. Casares, M. V. Jiménez, A. Meli, S.
Moneti, F. Vizza, V. Herrera, and R. A. Sánchez-Delgado,
"Metal Activation of Dibenzo[b,d]thiophene.
Reactivity of the C-S Insertion Product [MeC(CH2PPh2)3]IrH(h2-C,S-C12H8S)"
Organometallics, 1995, 14, 4850-4857.
68.
Bianchini,* V. Herrera, M. V. Jiménez, F. Laschi, A.
Meli, R. A. Sánchez-Delgado, F. Vizza, and P. Zanello,
"Redox-Induced Conversion Pathways in Rhodium and Iridium
Complexes Containing C-S Bond Cleaved Benzo[b]thiopene." Organometallics 1995, 14, 4390-4401.
67. Bianchini,*
A. Meli, V. Herrera, M. V. Jiménez, R. A. Sánchez-Delgado and
Francesco Vizza, "The Catalytic Transformation of Benzo[b]thiophene to
2-Ethylthiophenol by a Soluble Rhodium Complex: The Reaction
Mechanism Involves Ring Openening Prior to Hydrogenation." J. Am. Chem. Soc. 1995, 117, 8567-8575.
66.
Bacchi, C. Bianchini,* V. Herrera, M. V. Jiménez, C.
Mealli, A. Meli, S. Moneti, M. Peruzzini, R. A.
Sánchez-Delgado and F. Vizza, "Thiophene C-S Bond Cleavage
by Rhodium and Iridium. An Unprecedented Bridging Mode of the
Open C4H4S
Fragment." J. Chem. Soc.
Chem. Commun. 1995, 921-922.
65. M.
Rosales,* Y. Alvarado, M. Boves, R. Rubio, H. Soscún and R. A.
Sánchez-Delgado, "Kinetics and Mechanisms of Homogeneous
Catalytic Reactions. Part 3. Regioselective Reduction of
Quinoline Catalysed by [RuH(CO)(NCMe)2(PPh3)2]BF4."
Trans. Met. Chem. 1995, 20, 246-251.
64. Bianchini,*
P. Frediani, V. Herrera, M. V. Jiménez, A. Meli, L. Rincón, R.
A. Sánchez-Delgado and F. Vizza, "Homogeneous Reactions of
Thiophenes with Transition Metals: a Modelling Approach for
Elucidation of HDS Mechanism and and Effective Method for the
Synthesis of Unusual Organosulfur Compounds." J. Am. Chem. Soc. 1995, 117, 4333-4346.
63. L.
Rincón,* J. Terra, D.
Guenzburger and R. A. Sánchez-Delgado, "Theoretical Study
of the Pyramidal Geometry Around the Sulfur in the S-Bound Mode
of Coordination of Thiophene to the [Cp(CO)2Fe]+ Fragment", Organometallics 1995, 14, 1292-1296.
62.
Bianchini,* V. Jimenez, A. Meli, F. Vizza, V. Herrera
and R. A. Sánchez Delgado*, "HDS Model Systems. Opening,
Hydrogenation and Hydrodesulfurization of dibenzothiophene (DBT)
at Iridium. First Case of Catalytic HDS of DBT in Homogeneous
Phase", Organometallics,
1995, 14, 2342-2352.
61.
R. A. Sánchez-Delgado,* M. Rosales, M. A. Esteruelas
and L. A. Oro, "Homogeneous Catalysis by Osmium Complexes.
A review", J. Mol. Catal.,
1995, 96, 231-243
60.
Bianchini,* A. Meli, M. Peruzzini, F. Vizza, S. Moneti,
V. Herrera and R. A. Sánchez Delgado*, "HDS Model
Systems. Coordination, Opening and Hydrogenation of Benzo[b]thiophene at
Iridium", J. Am. Chem.
Soc., 1994, 116, 4370-4381
59.
Bianchini,* A. Meli, M. Peruzzini, F. Vizza, V. Herrera
and R. A. Sanchez-Delgado*, "HDS Model Systems.
2,3-Dihydrothiophene as an Intermediate in the Homogeneous
Hydrogenation of Thiophene to Tetrahydrothiophene at Iridium", Organometallics, 1994, 13, 721-730.
58.
R. A. Sánchez-Delgado*, V. Herrera, L. Rincón, A.
Andriollo and G. Martín, "Molecular Analogues of Surface
Species. 3. The Mechanism of the Regioselective Hydrogenation of
Benzothiophene by Use of [Rh(COD)(PPh3)2]PF6 as the Catalyst
Precursor. Kinetic and Theoretical Study", Organometallics 1994, 13, 553-561
57.
R. A. Sánchez-Delgado, "Breaking C-S Bonds with
Transition Metal Complexes. A Review of Molecular Approaches to
the Study of the Mechanisms of the Hydrodesulfurization
Reaction", J.Mol. Catal.
1994, 86, 287-307
56.
R. A. Sanchez-Delgado and M. Rosales, "Homogeneous
Hydrogenation Reactions Catalyzed by Ruthenium and Osmium
Complexes", Trends in
Inorganic Chemistry 1993, 3, 479-496.
55. R.
A. Sanchez-Delgado,* D. Rondón, A. Andriollo, V. Herrera, G.
Martín, and B. Chaudret, "Kinetics and Mechanism of the
Regioselective Hydrogenation of Quinoline Using [Rh(COD)(PPh3)2]PF6 as the Catalyst
Precursor", Organometallics
1993, 12, 4291-4296.
54. Bianchini,*
A. Meli, M. Peruzzini, F. Vizza, P. Frediani, V. Herrera and
R. A. Sanchez-Delgado*, "HDS Model Systems. Homogeneous
and Heterogeneous (Solid-Gas) Hydrogenation of Benzothiophene at
Iridium", J. Am. Chem.
Soc., 1993, 115, 7505-7506.
53.
R. A. Sánchez-Delgado*, K. Lazardi, L. Rincón, J. A.
Urbina,* A. J. Hubert and A. N. Noels, "Towards a Novel Metal-based
Chemotherapy Against Tropical Diseases. 1. Enhancement of the
Efficacy of Clotrimazole Against Trypanosoma cruzi by
Complexation to Ruthenium in RuCl2(clotrimazole)2",
J. Med. Chem., 1993, 36, 2041-2043.
52. R.
Sánchez-Delgado*, V. Herrera, C. Bianchini*, D. Masi and C.
Mealli, "Simultaneous Coordination of Hydrides and h1-S Thiophenes Made Possible at
Iridium", Inorg. Chem.,
1993, 32, 3766-3770.
51.
R. Sánchez-Delgado, "A Kinetic and Theoretical
Investigation of the Mechanism of the Homogeneous Hydrogenation
of Benzothiophene Catalyzed by [Rh(COD)(PPh3)2]PF6",
Advances in Catalyst
Design, M. Graziani and C. N. R. Rao (Eds.), World
Scientific Press, 1993,
Vol. 2, 95-110.
50.
Bianchini*,
A. Meli, M. Peruzzini, F. Vizza, P. Frediani, V. Herrera and
R. Sánchez-Delgado*, "Opening, Desulfurization, and
Hydrogenation of Thiophene at Iridium. An Experimental Study in
Homogeneous Phase", J.
Am. Chem. Soc. 1993,
115, 2731-2742
49.
M. Turizo Arango y R. Sánchez-Delgado,
"Hidrogenación homogénea selectiva de alquinos catalizada por el
complejo de osmio OsHCl(CO)(PPh3)3",
Química Actualidad y
Futuro (Medellín), 1992,
2, 57-61
48.
M. Rosales*, A. González, Y. Alvarado, R. Rubio, A. Andriollo and R. A.
Sánchez-Delgado, "Kinetics and mechanisms of homogeneous
catalytic reactions. 1. Hydrogenation of benzaldehyde catalyzed
by [RuH(CO)(NCMe)2(PPh3)2]BF4,
J. Mol. Catal., 1992, 75, 1-13
47.
R. A. Sánchez-Delgado*, M. Rosales and A. Andriollo,
"The chemistry and catalytic properties of ruthenium and osmium
complexes. 6. Synthesis and reactivity of [RuH(CO)(NCCH3)2(PPh3)2]BF4,
including the catalytic hydroformylation of hex-1-ene", Inorg. Chem., 1991, 30, 1170-1173
46. R.
A. Sánchez-Delgado, Molecular analogues of surface species
in HDS catalysis: metal complexes of thiophene and related
ligands and the mechanism of hydrogenation of benzothiophene, Advances in Catalyst
Design, M. Graziani and C. N. R. Rao (Eds.), World
Scientific Press, 1991,
214-231
45.
R. A. Sánchez-Delgado*, W. Y. Lee, S. R. Choi and M. J.
Jun, "The chemistry and catalytic properties of ruthenium
and osmium complexes. 5. Synthesis of new compounds containing
arsine ligands and catalytic activity in the homogeneous
hydrogenation of aldehydes", Trans. Met. Chem., 1991, 16, 241-244
44.
R. A. Sánchez-Delgado, "Análogos moleculares de
especies superficiales en HDS y HDN. Modelos organometálicos de
reacciones heterogéneas", Anales
XII Simposio Iberoamericano de Catalisis, 1990, 3, 742-753
43.
Chaudret*, F. Jalón, M. Pérez-Manrique, F. Lahoz, F. J.
Plou and R. A. Sánchez-Delgado, "A new and general method
for the preparation of novel π-derivatives of ruthenium [(C5Me5)Ru(arene)].
X-ray crystal structure of [(C5Me5)Ru2Cl2(py)2]PF6",
New J. Chem., 1990, 14, 331-338
42. Andriollo,
M. A. Esteruelas, V. Meyer, L. A. Oro*, R. A. Sánchez-Delgado,
E. Sola, C. Valero and H. Werner*, "Kinetic and
mechanistic investigation of the sequential hydrogenation of
phenylacetylene catalyzed by OsHCl(CO)(PR3)2",
J. Am. Chem. Soc., 1989, 111, 7431-7437
41.
F. Ruette*, N. Valencia and R. A. Sánchez-Delgado*,
"Molecular analogues of surface species. 2. A theoretical studie
of molybdenum carbonyl thiophene complexes: organometallic
models for the chemisorption of thiophene", J. Am. Chem. Soc., 1989, 111, 46-54.
40.
R. A. Sánchez-Delgado* and E. González, "Selective
hydrogenation of benzothiophene and quinoline catalyzed by Ru,
Os, Rh and Ir complexes", Polyhedron,
1989, 8, 1431-1436
39. P.
Dufour, L. Huang, A. Choplin, R. A. Sánchez-Delgado, A.
Theolier and J. M. Basset*, "Surface organometallic
chemistry: formation of the grafted dianionic cluster [Rh6(CO)15]2- upon adsorption of Rh6(CO)16 on a partially
hydroxylated magnesia", J.
Organomet. Chem., 1988,
354, 243-248
38.
N. Homs, A. Choplin, P. Ramírez de la Piscina, L.
Huang, E. Garbowski, R. A. Sánchez-Delgado and J. M. Basset*,
"Surface organometallic chemistry: the disproportionation of Co2(CO)8 on a MgO surface", Inorg. Chem., 1988, 27, 4030-4033
37. F.
Noels, A. Demonceau, E. Carlier, A. J. Hubert*, R. L.
Márquez-Silva and R. A. Sánchez-Delgado, "Competitive
cyclopropanation and cross-metathesis reactions of alkenes
catalysed by diruthenium tetrakis carboxylates", J. Chem. Soc. Chem. Commun.,
1988, 783-784
36. J.
Puga*, A. Arce, R. A. Sánchez-Delgado, A. Andriollo, D. Braga*
and F. Grepioni "Synthesis, reactivity and spectroscopic
studies on some tetranuclear osmium clusters. Structural
characterization of [HOs4(CO)12{m3-N(CO)CH3}][MPPh3]
(M = Au, Cu) and [PPN][H2Os4(CO)12(I)]",
J. Chem. Soc. Dalton
Trans., 1988,
913-923
35.
Choplin, B. Besson, L. D'Ornelas, R. A. Sánchez-Delgado
and J.M. Basset*, "Surface organometallic chemistry:
Hydrogenation of ethylene with Os3(CO)10(H)(OSi-)
and
reactivity of the molecular analogue Os3(CO)10(H)(OPh)",
J. Am. Chem. Soc., 1988, 110, 2783-2787
34.
R. A. Sánchez-Delgado*, A. Andriollo, J. Puga and G.
Martín, "Homogeneous catalysis by metal clusters. 2.
Hydrogenation of styrene by tetranuclear osmium clusters", Inorg. Chem. 1987, 26, 1867-1870
33.
L. D'Ornelas, A. Choplin, J.M Basset*, J. Puga and R.
A. Sánchez-Delgado*, "Surface organometallic chemistry:
the relative reactivity of carbonyl, hydride and halide ligands
in H4Os4(CO)12 and H3Os4(CO)12(I)
toward magnesia", Inorg.
Chem., 1986,
25, 4315-4316
32. R. A.
Sánchez-Delgado*, R. L. Márquez-Silva, J. Puga, A.
Tiripicchio* and M. Tiripicchio-Camellini, "Organometallic
models of the hydrodesulphurisation reaction. Synthesis of
[(h-thiophene)M(PPh3)2]PF6 (M = Rh, Ir) and X-ray
structure of the Rh derivative, the first example of a fully
characterised π-thiophene complex of an HDS-active metal", J. Organomet. Chem. 1986, 316, C35-C37
31.
J. Puga*, R. A. Sánchez-Delgado, J. Ascanio and D.
Braga*, "Conversion of a nitrile ligand into an amido
group on a cluster surface: X-ray characterization of [HOs4(CO)12{m3-N(CO)CH3}][MPPh3]
(M = Au, Cu)" J. Chem.
Soc. Chem. Commun., 1986, 1631-1633
30.
R. A. Sánchez-Delgado, "Estudios recientes sobre la
síntesis y propiedades catalíticas de complejos de metales del
grupo VIII", Actas X
Simposio Iberoamericano de Catalisis, 1986, 1, 91-106
29.
R. A. Sánchez-Delgado* and B. A. Oramas, "The
chemistry and catalytic properties of ruthenium and osmium
complexes. 4. A comparative study of the reduction of nitro
compounds under hydrogen, syngas and water gas", J. Mol. Catal., 1986, 36, 283-291
28.
R. A. Sánchez-Delgado*, N. Valencia, R. L.
Márquez-Silva, A. Andriollo and M. Medina, "The chemistry
and catalytic properties of ruthenium and osmium complexes. 3.
The development of highly active systems for the homogeneous
hydrogenation of aldehydes and ketones", Inorg. Chem., 1986, 24, 1106-1111
27.
R. A. Sánchez-Delgado*, U. Thewalt*, N. Valencia, R. L.
Márquez-Silva, A. Andriollo, J. Puga, H. Schöllhorn, H. P.
Klein and B. Fontal, "The chemistry and catalytic
properties of ruthenium and osmium complexes. 2. Synthesis and
characterization of new mononuclear and dinuclear complexes with
H-, PR3 and RCO2- ligands. X-ray
structures of OsBr(CO)(OCOCH3)(PPh3)2,
RuCl(CO)(OCOCH3)(PPh3)2 and
[PPh2Me][Ru2Cl2(m-Cl)3(CO)2(PPh3)4]", Inorg. Chem., 1986, 24, 1097-1106
26.
R. A. Sánchez-Delgado*, A. Andriollo, E. González, N.
Valencia, V. León and J. Espidel, "The chemistry and
catalytic properties of ruthenium and osmium complexes. Part 1.
Homogeneous catalysis of organic reactions by
bromocarbonylhydridotris(triphenylphosphine) osmium(II)", J. Chem. Soc. Dalton Trans.,
1985, 1859-1864
25.
J. Puga*, R. A. Sánchez-Delgado, A. Andriollo and D.
Braga*, "A reversible ligand supported metal framework
rearrangement. X-ray structure analysis of [PPN][H2Os4(CO)12(I)]",Organometallics, 1985, 4 , 2064-2066
24.
J. Puga*, R. A. Sánchez-Delgado and D. Braga*, "The
interaction of H3Os4(CO)12(I)
with [PPN][NO2].
Synthesis
and chemical characterization of [PPN][H2Os4(CO)12(I)]
and H3Os4(CO)11(NO).
Structure determination of the new nitrosyl cluster H3Os4(CO)11(NO)",
Inorg. Chem, 1985, 23, 3971-3974
23.
R. A. Sánchez-Delgado*, A. Andriollo, J. Ascanio, E.
González, G. Martín, J. Puga et M. Rosales, "Catalyse
homogène et chimie fine: l'utilization de complexes
mononucleaires et polynucleaires de l'osmium", Recueil des Travaux II
Colloque Franco-Vénézuélien de Catalyse (Paris), 1985, A1-A13
22.
R. A. Sánchez-Delgado, "La química de los complejos
de rutenio y osmio. Aspectos sintéticos, estructurales y
catalíticos", Actas 1er Coloquio de Quimica
Inorgánica de la Sociedad Chilena de Quimica, 1985, 45-54
21.
R. A. Sánchez-Delgado*, A. Andriollo, M. Medina y N.
Valencia, "Hidrogenación catalítica homogénea del enlace
C=O de aldehídos y cetonas utilizando complejos de rutenio y
osmio", Actas 1er Coloquio
Franco-Venezolano de Catalisis(1983), 1984, 192-199
20.
R. Alvarez, E. Carmona*, M. L. Poveda and R. A.
Sánchez-Delgado,*
"Carbon dioxide chemistry. The synthesis and properties of
trans-Mo(CO2)2(PMe3)4,
the first stable bis(carbon dioxide) adduct of a transition metal", J. Am. Chem. Soc., 1984, 106, 2731-2732
19.
R. A. Sánchez-Delgado*, J. Puga and M. Rosales,
"Homogeneous catalysis by metal clusters 1. Hydrogenation of
cyclohexene by use of trinuclear and tetranuclear osmium
complexes", J. Mol.
Catal. 1984,
24, 221-225.
18.
R. A. Sánchez-Delgado*, A. Andriollo and N. Valencia,
"Homogeneous hydrogenation of a,b-unsaturated aldehydes
catalyzed by ruthenium and osmium complexes", J. Mol. Catal. 1984, 24, 217-220.
17.
R. A. Sánchez-Delgado*, N. Valencia and A. Oramas,
"Homogeneous hydrogenation of cyclohexene by ruthenium
carboxylate complexes. Further evidence for a general
mechanism", Acta Cient.
Venez. 1984, 35, 228-231
16.
E. Carmona*, K. Döppert, J. M. Marín, M. L. Poveda and
R. A. Sánchez-Delgado*, "Seven coordinate halo and
dithiocarbamate trimethylphosphine derivatives of molybdenum(II)
and tungsten(II)", Inorg.
Chem., 1984,
23, 530-534
15.
R. A. Sánchez-Delgado*, A. Andriollo and N. Valencia,
"Bromocarbonylhydridotris (triphenylphosphine)osmium(II): a
versatile catalyst for homogeneous organic reactions", J. Chem. Soc. Chem. Commun.,
1983, 444-445
14.
R. Blackborow, R. Daroda y R. A. Sánchez-Delgado, "Rutas homogéneas
para la producción de combustibles y productos químicos a partir
del gas de síntesis utilizando catalizadores derivados de
metales de transición", Acta
Cient. Venez.. 1982,
33, 131-138.
13.
R. A. Sánchez-Delgado*, A. Andriollo, K. Döppert, C.
Ramírez and N. Valencia, "Homogeneus catalytic
hydrogenation of aldehydes by use of ruthenium carboxylate
complexes", Acta Cient.
Venez., 1982,
33, 23-25
12.
H. P. Klein, U. Thewal*, K. Döppert* und R. A.
Sánchez-Delgado, "Darstellung,
Struktur und Eigenschaften des Dreikernigen Titanocomplexes Cp2TiCl-O-TiCpCl-OTiClCp2.CHCl3.",
J. Organomet. Chem., 1982, 236, 189-195.
11.
K. Döppert*, R. A. Sánchez-Delgado, H. P. Klein und U.
Thewalt*, "Darstellung, Struktur und Eigenschaften von
Bis(cyclopentadienyl)oxalatotitan(IV) und Bis
(cyclopentadienyl)dimaleinatotitan(IV), J. Organomet. Chem. 1982, 233, 205-213
10.
R. A. Sánchez-Delgado, "Hidroformilación homogénea
de olefinas catalizada por complejos de rutenio", Anais do 6º Simposio
Iberoamericano de Catalise (1978), 1981, 4, 1297-1327
9.
R. A. Sánchez-Delgado*, A. Andriollo, O. L. de Ochoa,
T. Suárez and N. Valencia, "Homogeneous hydrogenation of
aldehydes to alcohols with ruthenium triphenylphosphine
complexes", J.
Organomet. Chem. , 1981, 209, 77-83
8.
R. A. Sánchez-Delgado*, I. Durán, J. Monfort y E.
Rodríguez, "A comparative study of the isomerization and
hydrogenation of hex-1-ene with soluble and silica-supported
ruthenium catalysts", J.
Mol. Catal., 1981,
11, 193-203
7.
K. Döppert* und R. A. Sánchez-Delgado, "Zur Bildung
von Monocyclopentadienyl titan(IV)aquocomplexen", J. Organomet. Chem. ,
1980, 210, C9-C10
6.
R. A. Sánchez-Delgado*, I. Durán, J. Monfort y E.
Rodríguez, "Catálisis homogénea vs. heterogénea:
isomerización e hidrogenación del hex-1-eno catalizadas por
dodecacarboniltrirutenio en solución y soportado sobre sílica",
Anales del 7º Simposio
Iberoamericano de Catálisis, 1980, 149-158
5.
R. A. Sánchez-Delgado* and O. L. de Ochoa,
"Homogeneous hydrogenation of ketones to alcohols with ruthenium
complex catalysts", J.
Organomet. Chem. 1980,
202, 427-430
4.
R. A. Sánchez-Delgado, "Catálisis homogénea:
principios y aplicaciones", Acta Cient. Venez., 1979, 30, 517-524
3.
R. A. Sánchez-Delgado* and O. L. de Ochoa,
"Homogeneous hydrogenation of aldehydes and ketones by use of
ruthenium triphenylphosphine complexes", J. Mol. Catal. 1979, 6, 303-305
2. R. A.
Sánchez-Delgado and G. Wilkinson*, "Interactions of
diphenylacetylene and other acetylenes with
hydridonitrosyltris(triphenylphosphine)ruthenium,
carbonylhydridotris (triphenylphosphine)-rhodium and -iridium",
J. Chem. Soc. Dalton
Trans. 1977,
804-809
1.
R. A. Sánchez-Delgado, J. S. Bradley and G. Wilkinson*,
"Further studies on the homogeneous hydroformylation of alkenes
by use of ruthenium complex catalysts", J. Chem. Soc. Dalton
Trans. 1976,
399-404.
Patents
1.
D. E. Paez, A. Andriollo, R. A. Sánchez-Delgado, N.
Valencia, R. E. Galiasso and F. Lopez-Linares,
“Process for the selective hydrogenation of heteroaromatic
sulfur-containing and nitrogen-containing compounds”, U.S. Patent 5,958,223 to
INTEVEP, S.A. (28 Sept. 1999).
2.
D. E. Paez, A. Andriollo, R. A. Sánchez-Delgado, N.
Valencia, F. Lopez-Linares and R. Galiasso, "A Catalyst System for the
Selective Hydrogenation of Heteroaromatic Sulfur-Containing
and Nitrogen-Containing Compounds, and Process for Preparing
and Using Same", U.S. Patent 5,981,421
to INTEVEP, S.A. (Nov. 1999).
3.
D. E. Paez, A. Andriollo, R. A. Sánchez-Delgado, N.
Valencia, F. Lopez-Linares and R. Galiasso, "A Catalyst System for the
Selective Hydrogenation of Heteroaromatic Sulfur-Containing
and Nitrogen-Containing Compounds, and Process for Preparing
and Using Same", U.S. Patent 5,753,584 to INTEVEP, S.A. (19
May 1998).
4.
D. E. Paez, A. Andriollo, R. A. Sánchez-Delgado, N.
Valencia, F. Lopez-Linares and R. Galiasso, "Sistema Catalítico para
la Hidrogenación Selectiva de Compuestos Heteroaromáticos
Conteniendo Azufre y Nitrógeno, y el Proceso para su
Preparación y Uso", Solicitud de Patente Venezolana 96-1630
(24 Sept. 1996).