ADVANCED ORGANIC CHEMISTRY
Fall, 1998
Week Date Topic
1 9/2
Introductory Topics on Structure & Bonding:
Bond angles, bond lengths, configuration,
conformation, electronegativity, dipole moment,
H-bonds, complexes, bond energies, thermochemistry,
solvation, kinetics, isotope effects, LFER's,
reaction coordinate diagrams.
2 9/9 Acidity and Basicity
3 9/16 Nucleophilic Substitution at Saturated Carbon
4 10/7 Anchimeric Assistance, Carbonium Ion Rearrangements
5 10/14 Anchimeric Assistance, Carbonium Ion Rearrangements
6 10/21 Esterification and Hydrolysis
7 10/28 Elimination Reactions
8 11/4 MIDTERM EXAMINATION
9 11/11 Addition Reactions
10 11/18 Aromaticity, Electrophilic Aromatic Substitution
11 11/25 Nucleophilic Aromatic Substitution
12 12/2 Radical Reactions
13 12/9 Pericyclic Reactions
14 12/16
Photochemistry
Reference Books
Jerry March, Advanced Organic Chemistry, Wiley-Interscience,
4th Ed., 1992.
T. H. Lowry & K. S. Richardson, Mechanism
and Theory in
Organic Chemistry, Harper & Row, 3rd Ed., 1987.
F. A. Carey & R. J. Sundberg, Advanced
Organic Chemistry,
Plenum, Third Ed., 1990.